Influences of Ga concentration on performances of CuInGaSe2 cells fabricated by sputtering-based method with ceramic quaternary target

Copper Indium Gallium Selenide (Cu(In,Ga)Se₂, CIGSe) absorbers with different Ga contents were prepared by sputtering CIGSe ceramic targets and post-annealing. CIGSe solar cell devices were fabricated with other functional layers. The device performances and absorber properties were investigated. Increasing Ga content led to an increase in V_OC and a decrease in J_SC. Ga was supposed to diffuse towards back contact during the annealing process. The best performance was obtained as the ratio of Ga/(In + Ga) reaches 0.32 with the efficiency of 13.8% and a V_OC of 537 mV.     

企业开展矿山修复业务的几点思考

目前,中国矿山生态修复中存在诸多历史遗留问题。国家着手推动矿山治理和生态修复,已经取得了一些成效,但仍存在资金需求缺口大,修复后矿山土地使用确权、土地流转、开发利用等方面的问题。从国家政策支持、治理资金出资模式等方面对矿山修复进行了思考。     

Inkjet-printed Ag@SDC core-shell nanoparticles as a high-performance cathode for low-temperature solid oxide fuel cells

This work demonstrates the superior thermostability of silver-based nanoparticle cathodes under continuous solid oxide fuel cell operation by coating the samarium-doped ceria (SDC) thin shell over silver nanoparticles. The Ag-core/SDC-shell (Ag@SDC) nanoparticles prepared by solvothermal synthesis (Ag core diameter = 48 nm; average SDC shell thickness = 2–5 nm) is inkjet-printed on electrolyte substrates as a thin film cathode. The Ag@SDC film survives the 48-h thermal annealing and its most porosities remain visibly un-agglomerated. The results of fuel cell current stability test show that the cell using the Ag@SDC nanoparticle cathode have only 3% of current degradation after 25 h, which is remarkably lower than that of the cell using the bare Ag nanoparticle cathode (96.1%). In addition, the electrochemical performance of the bare silver cathode in oxygen reduction reaction has significantly improved because of the enhanced surface oxygen adsorption/dissociation process provided by the SDC thin shell.     

Preparation and properties of modified graphene oxide incorporated waterborne polyurethane acrylate

In this study, a new modifier (KPG) was prepared by modifying graphene oxide with γ‐glycidoxypropyl trimethoxysilane (KH560) and polydimethylsiloxane (PDMS). KPG was in turn added to aqueous urethane acrylate for the fabrication of waterborne polyurethane polyacrylate emulsion modified with KH560‐PDMS composite (KPG/WPUA). Textural characterizations of the KPG/WPUA coating were achieved via Fourier transform infrared, SEM, TGA and AFM techniques, which revealed that the KPG/WPUA film possessed a smooth surface. The synthesized KPG/WPUA films were tested for mechanical properties, hydrophobicity and acid/water corrosion performance which suggested their highly hydrophobic surface. KPG/WPUA with 0.1% KPG showed a contact angle of 118.35°, 30.35° higher than that of pristine WPUA. The KPG/WPUA film exhibited higher thermal stability, i.e. a 5% weight loss temperature of 305 °C, which was 30 °C higher than that of pristine WPUA film. The Young's modulus and elongation at break of the KPG/WPUA film were 34.1 MPa and 74.88% respectively, which were higher than that of WPUA film. Furthermore, KPG/WPUA films exhibited greater resistance (without obvious blistering and the white spotting phenomenon) to H₂O₂, HCl and water corrosion than pristine WPUA. The superior performance of KPG/WPUA films was attributed to the network chain structure formed upon the introduction of KPG into WPUA. The outstanding performance of KPG/WPUA films in terms of mechanical properties, thermal stability and high resistance to acidic and water corrosion makes them interesting alternative contenders for target applications. © 2019 Society of Chemical Industry     

超高回采巷道顶部柔膜袋快速充填技术

针对阳泉煤业集团南庄煤矿8836运输巷局部超高,威胁安全生产的问题,实测了3个充填区域,设计了顶部柔膜袋快速充填方案,并进行了现场试验。结果表明:高水充填材料具备速凝早强特性,2 h强度1.25 MPa,28 d强度3.98 MPa,材料消耗约305 kg/m^3;效果考察表明,在工作面超前区,充填体下方单体柱受力均匀、明显,充填体接顶充分,工作面后方充填体垮落效果良好,未形成悬顶。     

A large-grain-size thick-film polycrystalline diamond detector for x-ray detection

A diamond film with a size of 6 × 6 × 0.5 mm³ is fabricated by electron-assisted chemical vapor deposition. Raman spectrum analysis, x-ray diffraction and scanning electron microscope images confirm the high purity and large grain size, which is larger than 300 μm. Its resistivity is higher than ${10}^{12}\,{\rm{\Omega }}\cdot {\rm{cm}}.$ Interlaced-finger electrodes are imprinted onto the diamond film to develop an x-ray detector. Ohmic contact is confirmed by checking the linearity of its current–voltage curve. The dark current is lower than 0.1 nA under an electric field of 30 kV cm⁻¹. The time response is 220 ps. The sensitivity is about 125 mA W⁻¹ under a biasing voltage of 100 V. A good linear radiation dose rate is also confirmed. This diamond detector is used to measure x-ray on a Z-pinch, which has a double-layer 'nested tungsten wire array'. The pronounced peaks in the measured waveform clearly characterize the x-ray bursts, which proves the performance of this diamond detector.     

Inhibition of stress corrosion cracking in 304 stainless steel through titanium ion implantation

The effects of titanium ion implantation on the stress corrosion cracking (SCC) behaviour of 304 austenitic stainless steel were studied. Slow strain rate tests (SSRTs) were conducted on 304 steel in air and in 5?wt-% NaCl solution. The microscopic effects of ion implantation were evaluated by Stopping and Range of Ions in Matter Procedures (SRIM). Fracture morphologies and microstructures were investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The fracture surfaces illustrate that ion implantation significantly inhibits the corrosion pits that initiate SCC. A dense passive film, which inhibits SCC, was formed during the ion implantation process. SCC initiation was restrained due to the dense dislocation nets that were generated by titanium ion implantation.

Highlights

• Ion implantation inhibits SCC susceptibility.

• The lack of Cr at the grain boundary leads to the expansion of SCC along the grain boundary.

• Implantation-induced damage leads to high-density dislocations.

• The surface was amorphised due to high-density dislocations.

     

A survey on analysis and implementation of state-of-the-art haze removal techniques

Haze is a poor-quality state described by the opalescent appearance of the atmosphere which reduces the visibility. It is caused by high concentrations of atmospheric air pollutants, such as dust, smoke and other particles that scatter and absorb sunlight. The poor visibility can result in the failure of multiple computer vision applications such as smart transport systems, image processing, object detection, surveillance etc. One of the major issues in the field of image processing is the restoration of images that are corrupted due to different degradations. Typically, the images or videos captured in the outside environment have low contrast, colour fade and restricted visibility due to suspended particles of the atmosphere that directly influence the image quality. This can cause difficulty in identifying the objects in the captured hazy images or frames. To address this problem, several image dehazing techniques have been developed in the literature, each of which has its own advantages and limitations, but effective image restoration remains a challenging task. In recent times, various learning (Machine learning & Deep learning) based methods greatly condensed the drawbacks of manual design of haze related features and reduces the difficulty in efficient restoration of images with less computational time and cost. The current state-of-the-art methods for haze free images, mainly from the last decade, are thoroughly examined in this survey. Moreover, this paper systematically summarizes the hardware implementations of various haze removal methods in real time. It is with the hope that this current survey acts as a reference for researchers in this scientific area and to provide a direction for future improvements based on current achievements.     

极端电场环境激励下的VO2相变性能研究与应用

为揭示VXOY薄膜场致相变规律,推广钒氧化物应用于卫星控制系统,指导氧化钒规模制备,将磁控溅射法和真空退火工艺相结合,在Al2O3陶瓷基片上制备出VXOY薄膜,降低了实验对仪器精度的要求,提高了实验的成功率。对基片进行磁控溅射镀膜,在管式炉中进一步氧化处理生成表面均匀的V2O5,然后进行高温退火处理,对不同退火条件下的生成的薄膜进行了XRD表征。测得了电场激励下VXOY薄膜的相变现象,验证了电场激励下焦耳热并非薄膜相变的主导因素;总结了不同组分下VXOY薄膜的相变规律,研究了不同V6O13含量对VO2薄膜临界相变电压的影响规律,可指导VXOY薄膜应用于微纳卫星等极端环境下的设备控制系统。     

Application of fuzzy image restoration in criminal investigation

The advancement of science and technology has a positive effect on the development of law disciplines. The development of algorithms and artificial intelligence also has a certain impact on judicial practice. Image restoration is a significant technique in image processing. It aims to objectively restore the content or quality of the original image from the degraded image. Image degradation is always generated in image transmission, such as distortion, blur. In modern video surveillance system, image restoration is significant for criminal investigation. However, image restoration based on conventional filter algorithms cannot achieve satisfactory performance. Thus, we first introduce the image restoration algorithms based on different degradation model. Then, we propose some applications of fuzzy image restoration in criminal investigation. We conduct experiments on both degraded images and videos and experimental results have shown the effectiveness of fuzzy image restoration applying to the criminal investigation.